Chirality in Liquid Crystals (Partially Ordered Systems)
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Durrer, N. Turok, and B. Saw, A. Doostmohammadi, V. Nier, L. Kocgozlu, S. Thampi, Y. Toyama, P. Marcq, C. Lim, J. Yeomans, and B. Nych, J. Fukuda, U. Ognysta, S. Ackerman and I. X 7 , Machon and G. X 6 , Posnjak, S. France 33 , Kurik and O. Volovik and O. JETP 58 , ]. Lavrentovich and M. Partially Ordered Systems edited by H. Kitzerow and C. Bahr Springer, New York, Pargellis, N. Lin, D. Miller, P. Bertics, C. Murphy, J. Lee, S. Munir, and S. Interfaces 8 , Alexander, B. Chen, E. Matsumoto, and R. Senyuk, Q. Liu, S. He, R. Kamien, R. Kusner, T. Lubensky, and I. Smalyukh, Topological Colloids , Nature London , Pairam, J.
Vallamkondu, V. Koning, B. Ellis, M. Bates, V. Vitelli, and A. Thus in some case greater positional order will be entropically favorable. This theory thus predicts that a solution of rod-shaped objects will undergo a phase transition, at sufficient concentration, into a nematic phase. Although this model is conceptually helpful, its mathematical formulation makes several assumptions that limit its applicability to real systems. This statistical theory, proposed by Alfred Saupe and Wilhelm Maier, includes contributions from an attractive intermolecular potential from an induced dipole moment between adjacent liquid crystal molecules.
The anisotropic attraction stabilizes parallel alignment of neighboring molecules, and the theory then considers a mean-field average of the interaction. Solved self-consistently, this theory predicts thermotropic nematic-isotropic phase transitions, consistent with experiment.
McMillan's model, proposed by William McMillan,  is an extension of the Maier—Saupe mean field theory used to describe the phase transition of a liquid crystal from a nematic to a smectic A phase. It predicts that the phase transition can be either continuous or discontinuous depending on the strength of the short-range interaction between the molecules. As a result, it allows for a triple critical point where the nematic, isotropic, and smectic A phase meet.
Although it predicts the existence of a triple critical point, it does not successfully predict its value. The model utilizes two order parameters that describe the orientational and positional order of the liquid crystal. The first is simply the average of the second Legendre polynomial and the second order parameter is given by:. The postulated potential energy of a single molecule is given by:. The potential is then used to derive the thermodynamic properties of the system assuming thermal equilibrium. It results in two self-consistency equations that must be solved numerically, the solutions of which are the three stable phases of the liquid crystal.
In this formalism, a liquid crystal material is treated as a continuum; molecular details are entirely ignored. Rather, this theory considers perturbations to a presumed oriented sample. The distortions of the liquid crystal are commonly described by the Frank free energy density.
One can identify three types of distortions that could occur in an oriented sample: 1 twists of the material, where neighboring molecules are forced to be angled with respect to one another, rather than aligned; 2 splay of the material, where bending occurs perpendicular to the director; and 3 bend of the material, where the distortion is parallel to the director and molecular axis. All three of these types of distortions incur an energy penalty.
They are distortions that are induced by the boundary conditions at domain walls or the enclosing container. The response of the material can then be decomposed into terms based on the elastic constants corresponding to the three types of distortions. Elastic continuum theory is a particularly powerful tool for modeling liquid crystal devices  and lipid bilayers. Scientists and engineers are able to use liquid crystals in a variety of applications because external perturbation can cause significant changes in the macroscopic properties of the liquid crystal system.
Both electric and magnetic fields can be used to induce these changes. The magnitude of the fields, as well as the speed at which the molecules align are important characteristics industry deals with. Special surface treatments can be used in liquid crystal devices to force specific orientations of the director. The ability of the director to align along an external field is caused by the electric nature of the molecules. Permanent electric dipoles result when one end of a molecule has a net positive charge while the other end has a net negative charge. When an external electric field is applied to the liquid crystal, the dipole molecules tend to orient themselves along the direction of the field.
Even if a molecule does not form a permanent dipole, it can still be influenced by an electric field. In some cases, the field produces slight re-arrangement of electrons and protons in molecules such that an induced electric dipole results. While not as strong as permanent dipoles, orientation with the external field still occurs. The electric energy per volume stored in the system is. In nematic liquid crystals, the polarization, and electric displacement both depend on the linearly on the direction of the electric field.
Then density of energy is ignoring the constant terms that do not contribute to the dynamics of the system . This means that the system will favor aligning the liquid crystal with the externally applied electric field. The effects of magnetic fields on liquid crystal molecules are analogous to electric fields. Because magnetic fields are generated by moving electric charges, permanent magnetic dipoles are produced by electrons moving about atoms. When a magnetic field is applied, the molecules will tend to align with or against the field.
Electromagnetic radiation, e. UV-Visible light, can influence light-responsive liquid crystals which mainly carry at least a photo-switchable unit. In the absence of an external field, the director of a liquid crystal is free to point in any direction. It is possible, however, to force the director to point in a specific direction by introducing an outside agent to the system. For example, when a thin polymer coating usually a polyimide is spread on a glass substrate and rubbed in a single direction with a cloth, it is observed that liquid crystal molecules in contact with that surface align with the rubbing direction.
The currently accepted mechanism for this is believed to be an epitaxial growth of the liquid crystal layers on the partially aligned polymer chains in the near surface layers of the polyimide. Several liquid crystal chemicals also align to a 'command surface' which is in turn aligned by electric field of polarized light. This process is called photoalignment.
The competition between orientation produced by surface anchoring and by electric field effects is often exploited in liquid crystal devices. Consider the case in which liquid crystal molecules are aligned parallel to the surface and an electric field is applied perpendicular to the cell. At first, as the electric field increases in magnitude, no change in alignment occurs.
However at a threshold magnitude of electric field, deformation occurs. Deformation occurs where the director changes its orientation from one molecule to the next. The occurrence of such a change from an aligned to a deformed state is called a Fredericks transition and can also be produced by the application of a magnetic field of sufficient strength. The Fredericks transition is fundamental to the operation of many liquid crystal displays because the director orientation and thus the properties can be controlled easily by the application of a field.
As already described, chiral liquid-crystal molecules usually give rise to chiral mesophases. This means that the molecule must possess some form of asymmetry, usually a stereogenic center. An additional requirement is that the system not be racemic : a mixture of right- and left-handed molecules will cancel the chiral effect. Due to the cooperative nature of liquid crystal ordering, however, a small amount of chiral dopant in an otherwise achiral mesophase is often enough to select out one domain handedness, making the system overall chiral.
Chiral phases usually have a helical twisting of the molecules. If the pitch of this twist is on the order of the wavelength of visible light, then interesting optical interference effects can be observed. The chiral twisting that occurs in chiral LC phases also makes the system respond differently from right- and left-handed circularly polarized light. These materials can thus be used as polarization filters. It is possible for chiral LC molecules to produce essentially achiral mesophases.
For instance, in certain ranges of concentration and molecular weight , DNA will form an achiral line hexatic phase. An interesting recent observation is of the formation of chiral mesophases from achiral LC molecules.
Specifically, bent-core molecules sometimes called banana liquid crystals have been shown to form liquid crystal phases that are chiral. The appearance mechanism of this macroscopic chirality is not yet entirely clear. It appears that the molecules stack in layers and orient themselves in a tilted fashion inside the layers.
These liquid crystals phases may be ferroelectric or anti-ferroelectric, both of which are of interest for applications. Chirality can also be incorporated into a phase by adding a chiral dopant , which may not form LCs itself. Twisted-nematic or super-twisted nematic mixtures often contain a small amount of such dopants. Liquid crystals find wide use in liquid crystal displays, which rely on the optical properties of certain liquid crystalline substances in the presence or absence of an electric field.
The liquid crystal alignment is chosen so that its relaxed phase is a twisted one see Twisted nematic field effect.
The device thus appears transparent. When an electric field is applied to the LC layer, the long molecular axes tend to align parallel to the electric field thus gradually untwisting in the center of the liquid crystal layer. In this state, the LC molecules do not reorient light, so the light polarized at the first polarizer is absorbed at the second polarizer, and the device loses transparency with increasing voltage. In this way, the electric field can be used to make a pixel switch between transparent or opaque on command.
Color LCD systems use the same technique, with color filters used to generate red, green, and blue pixels. Similar principles can be used to make other liquid crystal based optical devices. Liquid crystal tunable filters are used as electrooptical devices,  e. Thermotropic chiral LCs whose pitch varies strongly with temperature can be used as crude liquid crystal thermometers , since the color of the material will change as the pitch is changed. Liquid crystal color transitions are used on many aquarium and pool thermometers as well as on thermometers for infants or baths. Thus, liquid crystal sheets are often used in industry to look for hot spots, map heat flow, measure stress distribution patterns, and so on.
Liquid crystal in fluid form is used to detect electrically generated hot spots for failure analysis in the semiconductor industry. Liquid crystal lenses converge or diverge the incident light by adjusting the refractive index of liquid crystal layer with applied voltage or temperature. Generally, the liquid crystal lenses generate a parabolic refractive index distribution by arranging molecular orientations.
Therefore, a plane wave is reshaped into a parabolic wavefront by a liquid crystal lens. The focal length of liquid crystal lenses could be continuously tunable when the external electric field can be properly tuned. Liquid crystal lenses are a kind of adaptive optics. Imaging system can be benefited with focusing correction, image plane adjustment, or changing the range of depth-of-field or depth of focus.
Liquid crystal lens is one of the candidates to develop vision correction device for myopia and presbyopia eyes e. Liquid crystal lasers use a liquid crystal in the lasing medium as a distributed feedback mechanism instead of external mirrors. Emission at a photonic bandgap created by the periodic dielectric structure of the liquid crystal gives a low-threshold high-output device with stable monochromatic emission. Polymer dispersed liquid crystal PDLC sheets and rolls are available as adhesive backed Smart film which can be applied to windows and electrically switched between transparent and opaque to provide privacy.
Many common fluids, such as soapy water , are in fact liquid crystals. Soap forms a variety of LC phases depending on its concentration in water. From Wikipedia, the free encyclopedia. State of matter with properties of both conventional liquids and crystals. See also: Thermotropic crystal. See also: Biaxial nematic and Twisted nematic field effect. See also: Lyotropic liquid crystal and Columnar phase. See also: Pattern formation. Can the nematic to smectic A phase transition in liquid crystal states be characterized as a universal phase transition? See also: Liquid-crystal display.
Crystals That Flow — classic papers from the history of liquid crystals. Liquid Crystals Today. World Scientific Publishing. Patent 3,, , Issue date: November 17, Applied Physics Letters. Bibcode : ApPhL.. Electronics Lett.tdotacgramconstu.tk
Effect of Central Longitudinal Dipole Interactions on Chiral Liquid-Crystal Phases
Bibcode : Prama The names pyramidic or bowlic were proposed, but eventually it was decided to adopt the name conic. Retrieved June 6, Shibaev and Lui Lam eds. New York: Springer.
Molecular Crystals and Liquid Crystals. Case Western Reserve University. Archived from the original on November 25, Retrieved June 13, Liquid Crystals 2nd ed. Cambridge: Cambridge University Press. The Physics of Liquid Crystals. Oxford: Clarendon Press. Textures of Liquid Crystals. Weinheim: Wiley-VCH. Tuning the strength of directional entropic forces by means of particle rounding or the use of depletants allows for reconfiguration between achiral and homochiral crystals.
We rationalize our findings by quantifying the chirality strength of each particle, both from particle geometry and potential of mean force and torque diagrams. Using Monte Carlo simulations we show that chiral polyhedra exhibiting weak directional entropic forces self-assemble either an achiral crystal or a chiral crystal with limited control over the crystal handedness.
Chiral Crystallization of Ethylenediamine Sulfate. The optimal conditions for the crystallization of achiral ethylenediamine sulfate into large chiral crystals that are ideal for polarimetry studies and observation using Polaroid sheets are presented. This experiment is an ideal undergraduate experiment, which clearly demonstrates the chiral crystallization of an achiral molecule.
Density of photon states in dye-doped chiral nematic liquid crystal cells in the presence of losses and gain. We calculate the density of photon states DOS of the normal modes in dye-doped chiral nematic liquid crystal LC cells in the presence of various loss mechanisms.
Losses and gain are incorporated into the transmission characteristics through the introduction of a small imaginary part in the dielectric constant perpendicular and along the director, for which we assume no frequency dispersion. Theoretical results are presented on the DOS in the region of the photonic band gap for a range of values of the loss coefficient and different values of the optical anisotropy. The obtained values of the DOS at the photonic band gap edges predict a reversal of the dominant modes in the structure.
Our results are found to be in good agreement with the experimentally obtained excitation thresholds in chiral nematic LC lasers. The behavior of the DOS is also discussed for amplifying LC cells providing additional insight to the lasing mechanism of these structures. Field-induced phase transitions in chiral smectic liquid crystals studied by the constant current method.
In ferroelectric liquid crystals , phase transitions can be induced by an electric field. The current constant method allows these transition to be quickly localized and thus the E,T phase diagram of the studied product can be obtained. In this work, we make a slight modification to the measurement principles based on this method. This modification allows the characteristic parameters of ferroelectric liquid crystal to be quantitatively measured.
The use of a current square signal highlights a phenomenon of ferroelectric hysteresis with remnant polarization at null field, which points out an effect of memory in this compound.
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Sreenilayam, S. New chiral de Vries smectic liquid -crystalline compounds are designed, synthesized, and investigated for perspective applications in defect-free bistable surface-stabilized ferroelectric liquid-crystal displays. In these compounds, a 5-phenyl-pyrimidine benzoate core is terminated on one side by a tri- or tetra-carbosilane group linked through an alkoxy group and an alkyl spacer and on the opposite side terminated by a chiral 2-octanol group.
The stereogenic center contains either a methyl or perfluoromethyl functional group. Our results for 5-phenyl-pyrimidine benzoate core-based compounds support a recently drawn conclusion by Schubert et al. C 4, , Effect of anisotropy on defect mode peculiarities in chiral liquid crystals. The effect of anisotropy on defect mode peculiarities in cholesteric liquid crystals is investigated.
Two cases are considered. In the first case, it is assumed that the defect layer is non-absorbing, and the effect of refraction anisotropy on the reflection, relative photonic density of states and the total field intensity produced in the defect layer are studied. In the second case, the defect layer is assumed to be isotropic for refraction and anisotropic for absorption, and the influence of defect layer absorption anisotropy on reflection, absorption, relative photonic density of states and the total field intensity produced in the defect layer are investigated.
DMR , U. Fast-switching chiral nematic liquid-crystal mode with polymer-sustained twisted vertical alignment. We demonstrate a fast-switching liquid-crystal mode with polymer-sustained twisted vertical alignment. By optimizing the polymerization condition, a polymer microstructure with controlled orientation is produced. The polymer microstructure not only synergistically suppresses the optical bounce during field-induced homeotropic-twist transition but also shortens the response time significantly.
Theoretical analyses validate that the ground state free energy density is modified by the aligning field of the polymer microstructure, which affects the driving voltage of the device. The outcomes of this paper will enable the development of fast-switching and achromatic electro-optical and photonic devices. Chiral Responsive Liquid Quantum Dots. How to convert the weak chiral -interaction into the macroscopic properties of materials remains a huge challenge.
Here, this study develops highly fluorescent, selectively chiral -responsive liquid quantum dots liquid QDs based on the hydrophobic interaction between the chiral chains and the oleic acid-stabilized QDs, which have been designated as S QDs. The fluorescence spectrum and liquidity of thermal control demonstrate the fluorescence properties and the fluidic behavior of S QDs in the solvent-free state. Especially, S QDs exhibit a highly chiral -selective response toward 1R, 2S amino-1,2-diphenyl ethanol. It is anticipated that this study will facilitate the construction of smart chiral fluidic sensors.
More importantly, S QDs can become an attractive material for chiral separation. Chiral symmetry breaking by spatial confinement in tactoidal droplets of lyotropic chromonic liquid crystals. In many colloidal systems, an orientationally ordered nematic N phase emerges from the isotropic I melt in the form of spindle-like birefringent tactoids. In cases studied so far, the tactoids always reveal a mirror-symmetric nonchiral structure, sometimes even when the building units are chiral.
We report on chiral symmetry breaking in the nematic tactoids formed in molecularly nonchiral polymer-crowded aqueous solutions of low-molecular weight disodium cromoglycate. The parity is broken by twisted packing of self-assembled molecular aggregates within the tactoids as manifested by the observed optical activity. Fluorescent confocal microscopy reveals that the chiral N tactoids are located at the boundaries of cells. We explain the chirality induction as a replacement of energetically costly splay packing of the aggregates within the curved bipolar tactoidal shape with twisted packing.
The effect represents a simple pathway of macroscopic chirality induction in an organic system with no molecular chirality , as the only requirements are orientational order and curved shape of confinement. The conversion into 6,7-dihydro-5H-dibenz[c,e]azepine DAZ N-protected amides is a viable route for the determination of the absolute configuration of chiral 2-substituted carboxylic acids. The biphenyl moiety of DAZ, besides being a probe of chirality for the electronic circular dichroism ECD spectroscopy, makes these systems suitable for configuration assignment by exploiting the chirality amplification which occurs in nematic liquid crystals.
To assess the reliability of the liquid crystal method in detecting the absolute stereochemistry of chiral amides bound to a biphenyl group, we measured the helical twisting power of a series of DAZ-N-protected amides and compared these data with the results obtained from ECD measurements.
We will show that the liquid crystal method, corroborated by HTP predictions, is trustworthy with our biphenyl derivatives, even when ECD spectra are ambiguous for the presence of aryl moieties displaying strong UV absorptions in the same range of the biphenyl chromophore. Photo-manipulated photonic bandgap devices based on optically tristable chiral -tilted homeotropic nematic liquid crystal.
We report on the spectral properties of an optically switchable tristable chiral -tilted homeotropic nematic liquid crystal LC incorporated as a tunable defect layer in one-dimensional photonic crystal. By varying the polarization angle of the incident light and modulating the light intensity ratio between UV and green light, various transmission characteristics of the composite were obtained.
The hybrid structure realizes photo-tunability in transmission of defect-mode peaks within the photonic bandgap in addition to optical switchability among three distinct sets of defect modes via photoinduced tristable state transitions. Because the fabrication process is easier and less critical in terms of cell parameters or sample preparation conditions and the LC layer itself possesses an extra stable state compared with the previously reported bistable counterpart operating on the basis of biased-voltage dual-frequency switching, it has much superior potential for photonic applications such as a low-power-consumption multichannel filter and an optically controllable intensity modulator.
Tunable reflectance of an inverse opal- chiral nematic liquid crystal multilayer device by electric- or thermal-control. Bilayer IOP was fabricated by layer-by-layer assembly of polystyrene PS spheres with two different sizes and showed a reflectance in an extended range of the near-infrared region. Stokes parameter studies of spontaneous emission from chiral nematic liquid crystals as a one-dimensional photonic stopband crystal : experiment and theory. The helical structure of uniformly aligned chiral nematic liquid crystals results in a photonic stopband for only one sense of circular polarization.
The spectroscopic Stokes polarimeter is used to analyze spontaneous emission in the stopband. Highly polarized photoluminescence is found and the polarization properties vary with the excitation wavelength. Spontaneous emission is enhanced at the stopband edge and this Purcell effect is greater on excitation at wavelengths where the absorption coefficient is low.
This is interpreted as greater overlap between the excited molecules and the electrical modal field of the resonant modes at the stopband edge. Photoluminescence detected from the excitation face of the liquid crystal cell is less polarized because of photon tunneling. Fermi's golden rule in conjunction with Stokes vectors is used to model the polarization of emission taking multiple reflections at the interfaces of the cell into account. The discrepancy between the experiment and the theoretical model is interpreted as direct experimental evidence that virtual photons, which originate from zero point fluctuations of quantum space, are randomly polarized.
Chirality -controlled crystallization via screw dislocations. Chirality plays an important role in science from enantiomeric separation in chemistry to chiral plasmonics in nanotechnology. However, the understanding of chirality amplification from chiral building blocks to ordered helical superstructures remains a challenge. Here, we demonstrate that topological defects, such as screw dislocations, can drive the chirality transfer from particle to supramolecular structure level during the crystallization process.
By using a model system of chiral particles, which enables direct imaging of single particle incorporation into growing crystals , we show that the crystallization kinetic pathway is the key parameter for monitoring, via the defects, the chirality amplification of the crystalline structures from racemic to predominantly homohelical. We provide an explanation based on the interplay between geometrical frustration, racemization induced by thermal fluctuations, and particle chirality. Our results demonstrate that screw dislocations not only promote the growth, but also control the chiral morphology and therefore the functionality of crystalline states.
The product of photopolymerization could be seen by analysis of FTIR spectra both monomer and polymer. After UV curing process, peak for the carbonyl group at Liquid Crystals. Thermochromic liquid crystals , or TLCs, are a type of liquid crystals that react to changes in temperature by changing color. TLCs offered a new and potentially better method of visualizing the boundary layer transition in flight.
Hallcrest provided a liquid crystal formulation technique that afforded great control over the sensitivity of the liquid crystals to varying conditions. Method is of great use to industry, government and universities for aerodynamic and hydrodynamic testing. Additionally, Hallcrest manufactures TLC mixtures for cosmetic applications, and liquid crystal battery tester for Duracell batteries. The thermodynamic parameters of sorption and enantioselectivity of the chiral smectic liquid crystal 2-methylbutyl ester of 4- 4-decyloxybenzylideneamino -cinnamic acid.
The standard and excess thermodynamic functions of sorption were determined for 26 sorbates of the classes of substances specified. The helically twisted structure of the smectic liquid crystal was shown to play an important role in the mechanism of the chiral recognition of optical isomers of polar and low-polarity compounds under gas- liquid chromatography conditions.
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Enhancing and reducing chirality by opposite circularly-polarized light irradiation on crystalline chiral domains consisting of nonchiral photoresponsive W-shaped liquid crystal molecules. We found possible chirality enhancement and reduction in chiral domains formed by photoresponsive W-shaped molecules by irradiation with circularly polarized light CPL. The W-shaped molecules exhibit a unique smectic phase with spontaneously segregated chiral domains, although the molecules are nonchiral. The chirality control was generated in the crystalline phase, which shows chiral segregation as in the upper smectic phase, and the result appeared to be as follows: for a certain chiral domain, right-CPL stimuli enhanced the chirality , while left-CPL stimuli reduced the chirality , and vice versa for another chiral domain.
Interestingly, no domain-size change could be observed after CPL irradiation, suggesting some changes in the causes of chirality. In this way, the present system can recognize the handedness of the applied chiral stimuli. In other words, the present material can be used as a sensitive chiral -stimuli-recognizing material and should find invaluable applications, including in chiroptical switches, sensors, and memories as well as in chiral recognition. Liquid Crystals for Laser Applications. Meyer2 3 who, by means These tilted chiral smectic phases are classified according to the nature of the intermolecular I I packing within.
Aqueous cholesteric liquid crystals using uncharged rodlike polypeptides. Polypeptide vesicles by conformation-specific assembly. Ordered chiral macroporous hybrid silica-polypeptide composites. The aqueous, lyotropic liquid -crystalline phase behavior of an alpha helical polypeptide, has been studied using optical microscopy and X-ray scattering.
Solutions of optically pure polypeptide were found to form cholesteric liquid crystals at volume fractions that decreased with increasing average chain length. At very high volume fractions, the formation of a hexagonal mesophase was observed. The pitch of the cholesteric phase could be varied by a mixture of enantiomeric samples, where the pitch increased as the mixture approached equimolar.
The cholesteric phases could be untwisted, using either magnetic field or shear flow, into nematic phases, which relaxed into cholesterics upon removal of field or shear. We have found that the phase diagram of this polypeptide in aqueous solution parallels that of poly gamma-benzyl glutamate in organic solvents, thus providing a useful system for liquid-crystal applications requiring water as solvent. We have found that block copolymers composed of polypeptide segments provide significant advantages in controlling both the function and supramolecular structure of bioinspired self-assemblies.
Incorporation of the stable chain conformations found in proteins into block copolymers was found to provide an additional element of control, beyond amphiphilicity and composition that defines self-assembled architecture. The abundance of functionality present in amino acids, and the ease by which they can be incorporated into these materials, also provides a powerful mechanism to impart block copolypeptides with function.
This combination of structure and function work synergistically to enable significant advantages in the preparation of therapeutic agents as well as provide insight into design of self-assemblies beginning to approach the complexity of natural structures such as virus capsids. Spontaneous emission from radiative chiral nematic liquid crystals at the photonic band-gap edge: an investigation into the role of the density of photon states near resonance.
In this article, we investigate the spontaneous emission properties of radiating molecules embedded in a chiral nematic liquid crystal , under the assumption that the electronic transition frequency is close to the photonic edge mode of the structure, i. We take into account the transition broadening and the decay of electromagnetic field modes supported by the so-called "mirrorless"cavity. We employ the Jaynes-Cummings Hamiltonian to describe the electron interaction with the electromagnetic field, focusing on the mode with the diffracting polarization in the chiral nematic layer.
As known in these structures, the density of photon states, calculated via the Wigner method, has distinct peaks on either side of the photonic band gap, which manifests itself as a considerable modification of the emission spectrum. We demonstrate that, near resonance, there are notable differences between the behavior of the density of states and the spontaneous emission profile of these structures.
In addition, we examine in some detail the case of the logarithmic peak exhibited in the density of states in two-dimensional photonic structures and obtain analytic relations for the Lamb shift and the broadening of the atomic transition in the emission spectrum. The dynamical behavior of the atom-field system is described by a system of two first-order differential equations, solved using the Green's-function method and the Fourier transform.
The emission spectra are then calculated and compared with experimental data. White, and T. Liquid Crystals in Chromatography. Spontaneous helix formation in non- chiral bent-core liquid crystals with fast linear electro-optic effect. Sreenilayam, Sithara P.
Liquid crystals LCs represent one of the foundations of modern communication and photonic technologies. Present display technologies are based mainly on nematic LCs, which suffer from limited response time for use in active colour sequential displays and limited image grey scale. Herein we report the first observation of a spontaneously formed helix in a polar tilted smectic LC phase SmC phase of achiral bent-core BC molecules with the axis of helix lying parallel to the layer normal and a pitch much shorter than the optical wavelength. Even more importantly, defect-free alignment is easily achieved for the first time for a BC mesogen, thus providing potential use in large-scale devices with fast linear and thresholdless electro-optical response.
Effects of molecular chirality on self-assembly and switching in liquid crystals at the cross-over between rod-like and bent shapes. A bent-core compound derived from a 4-cyanoresorcinol core unit with two terephthalate based rod-like wings and carrying chiral 3,7-dimethyloctyloxy side chains has been synthesized in racemic and enantiomerically pure form and characterized by polarizing microscopy, differential scanning calorimetry, X-ray diffraction and electro-optical investigations to study the influence of molecular chirality on the superstructural chirality and polar order in lamellar liquid crystalline phases.
Moreover, the mechanism of electric field induced molecular reorganization changes from a rotation around the molecular long axis in the racemate to a rotation on the tilt-cone for the S -enantiomer. At reduced temperature sterically induced polarization, due to the bent molecular shape, becomes dominating, leading to much higher polarization values, thus providing access to high polarization ferroelectric materials with weakly bent compounds having only "weakly chiral " stereogenic units.
Comparison with related compounds indicates that the strongest effects of chirality appear for weakly bent molecules with a relatively short coherence length of polar order, whereas for smectic phases with long range polar order the effects of the interlayer interfaces can override. Cholesteric liquid crystals with a helical pitch gradient: Spatial distribution of the concentration of chiral groups by Raman mapping in relation with the optical response and the microstructure.
Cholesteric liquid crystals CLC selectively reflect light when the helical pitch is of the order of the wavelength of the incident beam propagating along the helix axis. The wavelength bandwidth, related to the optical anisotropy, is typically limited to a few tens of nanometers in the visible part of the spectrum, which is insufficient for applications such as white-or-black polarizer-free reflective displays and smart windows for the control of the solar light and heat.
A way to make cholesteric films reflecting in a broad wavelength band consists in associating various cholesteric pitches in the same film. In this work, it is shown how a study by confocal micro Raman spectrometry mapping makes it possible to have access to information accounting for the local organization of CLCs in the case of graded pitch materials. These investigations will be correlated to the optical response and the transverse microstructure of the CLC material as investigated by transmission electron microscopy. Besides an easy measurement of the Raman spectrum gives the opportunity to quantify the relative ratio of the mesogenic species and thus to go up by a simple way to the pitch of the helical structure.
Ultrasound liquid crystal lens. A variable-focus lens using a combination of liquid crystals and ultrasound is discussed. The lens uses a technique based on ultrasound vibration to control the molecular orientation of the liquid crystal. The lens structure is simple, with no mechanical moving parts and no transparent electrodes, which is helpful for device downsizing; the structure consists of a liquid crystal layer sandwiched between two glass substrates with a piezoelectric ring. The tens-of-kHz ultrasonic resonance flexural vibration used to excite the lens generates an acoustic radiation force on the liquid crystal layer to induce changes in the molecular orientation of the liquid crystal.
The orientations of the liquid crystal molecules and the optical characteristics of the lens were investigated under ultrasound excitation. Clear optical images were observed through the lens, and the focal point could be controlled using the input voltage to the piezoelectric ring to give the lens its variable-focus action. Chiral liquid phase of simple quantum magnets. The transition is induced by an easy-plane single-ion anisotropy D. We show that beyond mean field the phase diagram is very different and includes an intermediate, partially ordered chiral liquid phase.
This chiral liquid phase is characterized by a finite vector chirality without long-range dipolar magnetic order. In our analytical treatment, the chiral phase appears for arbitrarily small J z because the magnon-magnon attraction becomes singular near the single-magnon condensation transition.
Liquid crystal - Wikipedia
This phase exists in a finite range of D and transforms into the magnetically ordered state at some Dc. In conclusion, we corroborate our analytic treatment with numerical density matrix renormalization group calculations. Thermotropic Ionic Liquid Crystals.
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The present review describes the mesomorphic properties displayed by organic, as well as metal-containing ionic mesogens. In addition, a short overview on the ionic polymer and self-assembled liquid crystals is given. Potential and actual applications of ionic mesogens are also discussed. The last five years' achievements in the synthesis and investigation of thermotropic ionic liquid crystals are reviewed. Elasticity-driven partial demixing in cholesteric liquid crystal films.
We discuss the partial demixing of a chiral nematic mixture of a chiral and an achiral compound, induced by inhomogeneous confinement between substrates. While the effect is tiny in low molar mass mixtures, it is predicted to be noticeable in polymeric systems. The potential of the effect for improving performance of liquid crystal based photonic devices is discussed. Chiral ionic liquids in chromatographic and electrophoretic separations. This report provides an overview of the application of chiral ionic liquids CILs in separation technology, and particularly in capillary electrophoresis and both gas and liquid chromatography.
There is a large number of CILs that have been synthesized and designed as chiral agents. However, only a few have successfully been applied in separation technology. Even though this application of CILs is still in its early stages, the scientific interest is increasing dramatically. This article is focused on the use of CILs as chiral selectors, background electrolyte additives, chiral ligands and chiral stationary phases in electrophoretic and chromatographic techniques. Different examples of CILs, which contain either a chiral cation, a chiral anion or both, are presented in this review article, and their major advantages along with their potential applications in chiral electrophoretic and chromatographic recognition are discussed.
All rights reserved. Liquid Crystal Colloids. Colloids are abundant in nature, science, and technology, with examples ranging from milk to quantum dots and the colloidal atom paradigm. Similarly, liquid crystal ordering is important in contexts ranging from biological membranes to laboratory models of cosmic strings and liquid crystal displays in consumer devices. Some of the most exciting recent developments in both of these soft matter fields emerge at their interface, in the fast-growing research arena of liquid crystal colloids.
Mesoscale self-assembly in such systems may lead to artificial materials and to structures with emergent physical behavior arising from patterning of molecular order and nano- or microparticles into precisely controlled configurations. Liquid crystal colloids show exceptional promise for new discovery that may impinge on composite material fabrication, low-dimensional topology, photonics, and so on. Starting from physical underpinnings, I review the state of the art in this fast-growing field, with a focus on its scientific and technological potential.
Circularly polarized guided modes in dielectrically chiral photonic crystal fiber. The effect of dielectric chirality on the polarization states and mode indices of guided modes in photonic crystal fiber PCF is investigated by a modified plane-wave expansion PWE method. Using a solid-core chiral PCF as a numerical example, we show that circular polarization is the eigenstate of the fundamental mode. Mode index divergence between right-handed circularly polarized RCP and left-handed circularly polarized LCP states is demonstrated.
Chirality 's effect on mode index and circular birefringence CB in such a PCF is found to be similar to that in bulk chiral media. Paintable band-edge liquid crystal lasers. In this paper we demonstrate photonic band-edge laser emission from emulsion-based polymer dispersed liquid crystals.
The lasing medium consists of dye-doped chiral nematic droplets dispersed within a polymer matrix that spontaneously align as the film dries. Such lasers can be easily formed on single substrates with no alignment layers. The system combines the self-organizing periodic structure of chiral nematic liquid crystals with the simplicity of the emulsion procedure so as to produce a material that retains the emission characteristics of band-edge lasers yet can be readily coated.
Sequential and stacked layers demonstrate the possibility of achieving simultaneous multi-wavelength laser output from glass, metallic, and flexible substrates. Thermodynamic and kinetic parameters are of prime importance for designing crystallization processes. In this article, Preferential Crystallization , as a special approach to carry out enantioselective crystallization , is described to resolve the enantiomers of the chiral fungicide fenamidone. In preliminary investigations the melting behavior and solid- liquid equilibria in the presence of solvents were quantified.
The analyses revealed a stable solid phase behavior of fenamidone in the applied solvents.
Controlling chirality with helix inversion in cholesteric liquid crystals
Based on the results obtained, a two-step crystallization route was designed and realized capable of providing highly pure enantiomers. An initial Preferential Crystallization of the racemate was performed prior to crystallizing the target enantiomer preferentially out of the enriched mother liquor. Chirality , Chiral photonic crystal fibers with single mode and single polarization. Chiral photonic crystal fiber PCF with a solid core is numerically investigated by a modified chiral plane-wave expansion method. The effects of structural parameters and chirality strength are analyzed on single-polarization single-mode range and polarization states of guided modes.
The simulation demonstrates that the chiral photonic crystal fiber compared to its achiral counterpart possesses another single-circular-polarization operation range, which is located in the short-wavelength region. The original single-polarization operation range in the long-wavelength region extends to the short wavelength caused by introducing chirality. Then this range becomes a broadened one with elliptical polarization from linear polarization. With increase of chirality , the two single-polarization single-mode ranges may fuse together.
By optimizing the structure, an ultra-wide single-circular-polarization operation range from 0. Chiral ionic liquids with a focus on their applications in asymmetric Michael additions and related reactions were reviewed. The examples were classified on the basis of the mode of asymmetric induction e. Many reports demonstrate the recyclability of ionic liquid -tagged pyrrolidines.
Liquid crystals in tribology. Two decades ago, the literature dealing with the possible applications of low molar mass liquid crystals , also called monomer liquid crystals MLCs , only included about 50 references. Today, thousands of papers, conference reports, books or book chapters and patents refer to the study and applications of MLCs as lubricants and lubricant additives and efforts are made to develop new commercial applications.
The development of more efficient lubricants is of paramount technological and economic relevance as it is estimated that half the energy consumption is dissipated as friction. MLCs have shown their ability to form ordered boundary layers with good load-carrying capacity and to lower the friction coefficients, wear rates and contact temperature of sliding surfaces, thus contributing to increase the components service life and to save energy.
Finally, new lubricating system composed of MLC blends with surfactants, ionic liquids or nanophases are considered. Influence of a change in helical twisting power of photoresponsive chiral dopants on rotational manipulation of micro-objects on the surface of chiral nematic liquid crystalline films. Herein we report a group of five planar chiral molecules as photon-mode chiral switches for the reversible control of the self-assembled superstructures of doped chiral nematic liquid crystals.
The chiral switches are composed of an asymmetrically substituted aromatic moiety and a photoisomerizing azobenzene unit connected in a cyclic manner through methylene spacers of varying lengths. All the molecules show conformational restriction in the rotation of the asymmetrically substituted aromatic moiety in both the E and Z states of the azobenzene units resulting in planar chirality with separable enantiomers. Our newly synthesized compounds in pure enantiomeric form show high helical twisting power HTP in addition to an improved change in HTP between the E and Z states.
The molecule with a diphenylnaphthalene unit shows the highest ever known initial helical twisting power among chiral dopants with planar chirality. In addition to the reversible tuning of reflection colors, we employed the enantiomers of these five compounds in combination with four nematic liquid crystalline hosts to study their properties as molecular machines; the change in HTP of the chiral dopant upon photoisomerization induces rotation of the texture of the liquid crystal surfaces.
Importantly, this study has revealed a linear dependence of the ratio of the difference between HTPs before and after irradiation against the absolute value of the initial HTP, not the absolute value of the change in helical twisting power between two states, on the angle of rotation of micro-objects on chiral nematic liquid crystalline films. This study has also revealed that a change in irradiation intensity does not affect the maximum angle of rotation, but it does affect the speed of rotational reorganization of the cholesteric helix.
Criteria of backscattering in chiral one-way photonic crystals.